Interactions of Randomly Disordered Molecules

Abstract
Some generalizations of previous theoretical expressions for the mean potential energy of interaction between two randomly disordered molecules have been derived and have been generalized to interactions in a molecular lattice. Values of the heats of vaporization of some tetrahedral molecules and halogens have been calculated, with results in reasonable agreement with experimental values. Application of the theory to the heat of sublimation of a disordered solid, hexachloroethane, is also discussed.

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