The Structure and Dynamics of Liquids
- 1 September 1941
- journal article
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 12 (9), 669-679
- https://doi.org/10.1063/1.1712959
Abstract
By coordinating our information on viscosity, diffusion, melting, and other rate and thermodynamic properties, we arrive at a detailed picture of liquid structure. Thus we find that a liquid is best thought of as a solid to which a large number of empty equilibrium positions are added. In fact the expansion on melting, as well as the expansion with a rise in temperature, arises almost entirely from this introduction of new equilibrium positions, and only to a minor extent from lattice expansion. We shall obtain information as to the number, size and energy of formation of these empty lattice points.Keywords
This publication has 17 references indexed in Scilit:
- Absolute Rates of Solid Reactions: Diffusion.The Journal of Physical Chemistry, 1940
- An Elementary Theory of CondensationThe Journal of Chemical Physics, 1939
- Experimentelle Untersuchungen der Strömungsdoppelbrechung molekularer FlüssigkeitenThe European Physical Journal A, 1939
- Critical and co-operative phenomena. III. A theory of melting and the structure of liquidsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1939
- Order and Disorder in Liquid Solutions.The Journal of Physical Chemistry, 1939
- The Deduction of Reaction Mechanisms from the Theory of Absolute RatesThe Journal of Chemical Physics, 1937
- Change of volume on mixing and the equations for non-electrolyte mixturesTransactions of the Faraday Society, 1937
- The Application of Equations for the Chemical Potentials to Partially Miscible SolutionsJournal of the American Chemical Society, 1935
- The Rotational Motion of Molecules in CrystalsPhysical Review B, 1930
- The Viscosity of Liquids. V. The Ideality of the System: Benzene - Benzyl Benzoate and the Validity of the Bingham Fluidity ForumulaJournal of the American Chemical Society, 1921