A PULSED ION SOURCE FOR THE STUDY OF UNIMOLECULAR AND BIMOLECULAR REACTIONS OF GAS-PHASE IONS
- 1 January 1965
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 43 (1), 159-174
- https://doi.org/10.1139/v65-019
Abstract
A pulsed ion source has been constructed for use with a magnetic-deflection mass spectrometer. With this source the time between ion formation and withdrawal for analysis can be controlled and varied in a known manner. The design and operating characteristics of the source are discussed and a technique is described for the measurement of ion withdrawal times using the pulsing technique. The rate constant for the ion molecule reaction[Formula: see text]has been determined for the reaction of thermal energy ions using reaction time as the experimental variable. The equivalent reactions in the deuteriomethanes have also been studied. Preliminary results obtained in the study of the unimolecular fragmentation of the cyclohexadiene, toluene, and spiroheptadiene parent ions are presented.Keywords
This publication has 4 references indexed in Scilit:
- Nature of Metastable Peaks in Mass SpectraThe Journal of Chemical Physics, 1964
- ION–MOLECULE REACTIONS STUDIED BY TIME-OF-FLIGHT MASS SPECTROMETRYCanadian Journal of Chemistry, 1964
- Cross Sections for Ionization by ElectronsJournal of the American Chemical Society, 1957
- Absolute Rate Theory for Isolated Systems and the Mass Spectra of Polyatomic MoleculesProceedings of the National Academy of Sciences, 1952