Heat-Capacity Lag in Gas Dynamics
- 1 March 1946
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 14 (3), 150-164
- https://doi.org/10.1063/1.1724115
Abstract
The existence of energy dissipations in gas dynamics, which must be attributed to a lag in the vibrational heat capacity of the gas, has been established both theoretically and experimentally. The flow about a very small impact tube is discussed. It is shown that total‐head defects due to heat‐capacity lag during and after the compression of the gas at the nose of an impact tube are to be anticipated. Experiments quantitatively verifying these anticipations in carbon dioxide are discussed. A general theory of the dissipations in a more general flow problem is developed and applied to some special cases. It is pointed out that energy dissipations due to this effect are to be anticipated in turbines. Dissipations of this kind might also introduce errors in cases in which the flow of one gas is used in an attempt to simulate the flow of another gas. Unfortunately, the relaxation times of most of the gases of engineering importance have not been studied. A new method of measuring the relaxation time of gases is introduced in which the total‐head defects observed with a specially shaped impact tube are compared with theoretical considerations. A parameter is thus evaluated in which the only unknown quantity is the relaxation time of the gas. This method has been applied to carbon dioxide and has given consistent results for two impact tubes at a variety of gas velocities.Keywords
This publication has 10 references indexed in Scilit:
- Effects of Heat Capacity Lag in Gas DynamicsThe Journal of Chemical Physics, 1942
- Measurements on the absorption of sound in CO2 gas, in CO2 containing small quantities of H2, D2, H2O, D2O and also in mixtures of CO2 and O2. Collision efficienciesPhysica, 1939
- Supersonic PhenomenaReviews of Modern Physics, 1939
- Thermodynamic Functions of Nitrous Oxide and Carbon Dioxide1Journal of the American Chemical Society, 1934
- Acoustical Studies. IV. The Collision Efficiencies of Various Molecules in Exciting the Lower Vibrational States of Ethylene, Together with Some Observations Concerning the Excitation of Rotational Energy in HydrogenThe Journal of Chemical Physics, 1934
- Acoustical Studies. III. The Rates of Excitation of Vibrational Energy in Carbon Dioxide, Carbon Disulfide and Sulfur DioxideThe Journal of Chemical Physics, 1934
- The Interpretation of the Anomalous Sound-Absorption in Air and Oxygen in Terms of Molecular CollisionsThe Journal of the Acoustical Society of America, 1933
- The Absorption of Sound in Air, in Oxygen, and in Nitrogen—Effects of Humidity and TemperatureThe Journal of the Acoustical Society of America, 1933
- The Vibrational Levels of Linear Symmetrical Triatomic MoleculesPhysical Review B, 1932
- ber den Ramaneffekt des KohlendioxydsThe European Physical Journal A, 1931