Chemoselective Oxidation of Secondary Hydroxy Functions Catalyzed by [PMo12O40]3-[C5H5N+(CH2)15CH3]3
- 1 April 1986
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 16 (5), 537-541
- https://doi.org/10.1080/00397918608078769
Abstract
The epoxidation of allylic alcohols with H2O2 catalyzed by a new Mo-species, [PMo12O40]3−[C5H5N+(CH2)15CH3]3 (MPCP), prepared from 12-molybdatophosphoric acid (H3PMo12O40) and cetylpyridinium chloride [C5H5N+(CH2)15CH3 · Cl−], has recently rep0rted.) The high regioselectivity for the epoxidation by this MPCP-H2O2 system was comparable to that of Sharpless method using t-BuOOH as oxidant.Keywords
This publication has 6 references indexed in Scilit:
- Chemoselective oxidation with molybdenum catalyst-t-butyl hydroperoxideTetrahedron Letters, 1984
- Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by [PMO12O40]3-[C5H5N+(CH2)15CH3]3Synthetic Communications, 1984
- Highly selective oxidation of secondary hydroxyl functions using the VO(acac)2-tBuOOH SYSTEMTetrahedron Letters, 1983
- Selective oxidation with t-butyl hydroperoxide and aluminium reagentsTetrahedron Letters, 1980
- Stereoselective epoxidation of acyclic allylic alcohols. A correction of our previous work.Tetrahedron Letters, 1979
- Oxidation of alcohols by molybdenum and tungsten peroxo complexesThe Journal of Organic Chemistry, 1979