Evidence for a ruthenium dihydride species as the active catalyst in the RuCl2(PPh3)-catalyzed hydrogen transfer reaction in the presence of base

Abstract

The role of the base in RuCl₂(PPh₃)₃-catalyzed hydrogen transfer reactions is to generate a highly active RuH₂(PPh₃)₃ catalyst from the dichloride via two consecutive alkoxide displacement–β-elimination sequences.