A highly stereoselective and general synthesis of conjugated trans,trans-dienes and trans-alkyl ketones via hydroboration

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Abstract
A highly stereoselective (98–99%) and general synthesis of conjugated trans,trans-dienes and trans-alkenyl ketones involving a novel class of organoborane [1-chloroalk-1-enyl-(1,1,2-trimethylpropyl)boranes (1)] is reported.