EFFECT OF LATTICE DISTORTION ON THE DEBYE–WALLER FACTOR: I. EXTENDED INTERNAL DEFECTS

Abstract

A model is introduced in which a Mössbauer atom in an extended internal defect is replaced by a point defect in a perfect lattice, with coupling equal to that in the extended defect. Lattice distortions are considered which are typical for extended defects, with 5 and 10% dilatation and compression, effective coupling constants in nearest-neighbor harmonic approximation are estimated for these cases for a monatomic cubic crystal with Morse potential interaction, and Visscher's data are then used to estimate the fractional change in the Debye–Waller factor, e^−2W. Decreases of 14 and 38% are found in e^−2W for 5 and 10%, respectively, of lattice dilatation in extended defects, using parameters that are typical of monatomic metals.