Phosphorescence Enhancement Triggered by Π Stacking in Solid-State [Cu(N−N)(P−P)]BF4 Complexes
- 26 January 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Langmuir
- Vol. 25 (4), 2068-2074
- https://doi.org/10.1021/la803822s
Abstract
In this article, we report a phosphorescence enhancement phenomenon of [Cu(N−N)(P−P)]BF4 complexes in the solid state. The phosphorescence enhancement phenomenon is composed of three features: (1) an obvious emission blue shift, (2) a greatly enhanced photoluminescence quantum yield, and (3) a longer excited-state lifetime. Systematic analyses prove that the main cause of this phenomenon is nonradiative process suppression triggered by the π stacking between [Cu(N−N)(P−P)]BF4 molecules. The phorsphorescence enhancement widely exists in [Cu(N−N)(P−P)]BF4 complexes because of the π surfaces in their diimine ligands.Keywords
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