Enantioselective Total Synthesis of (+)-Salvileucalin B
- 21 December 2010
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 133 (4), 774-776
- https://doi.org/10.1021/ja110192b
Abstract
An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate.This publication has 21 references indexed in Scilit:
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