On the Role of CO2 in NHC-Catalyzed Oxidation of Aldehydes
- 12 April 2011
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 13 (9), 2422-2425
- https://doi.org/10.1021/ol2006538
Abstract
NHC-catalyzed oxidations using carbon dioxide as the stoichiometric oxidant have been carefully investigated. These studies support a secondary role of CO2 in suppressing side reactions and exogenous oxygen as the actual oxidant.Keywords
This publication has 36 references indexed in Scilit:
- N-Heterocyclic Carbene-Mediated Oxidative Esterification of Aldehydes: Ester Formation and Mechanistic StudiesThe Journal of Organic Chemistry, 2011
- Efficient Catalytic, Oxidative Lactonization for the Synthesis of Benzodioxepinones Using Thiazolium-Derived Carbene CatalystsOrganic Letters, 2010
- The Catalytic Role of N-Heterocyclic Carbene in a Metal-Free Conversion of Carbon Dioxide into Methanol: A Computational Mechanism StudyJournal of the American Chemical Society, 2010
- Isotope Effect, Mechanism, and Origin of Catalysis in the Decarboxylation of MandelylthiaminJournal of the American Chemical Society, 2010
- Synthesis of Amides and Lactams in Supercritical Carbon DioxideThe Journal of Organic Chemistry, 2009
- Oxidative carboxylation of arylaldehydes with water by a sulfoxylalkyl-substituted N-heterocyclic carbene catalystOrganic & Biomolecular Chemistry, 2009
- N‐Heterocyclic Carbenes as Efficient Organocatalysts for CO2 Fixation ReactionsAngewandte Chemie International Edition, 2009
- N-Heterocyclic carbene-catalyzed oxidationsTetrahedron, 2008
- On the Mechanism of Thiamine Action. IV.1 Evidence from Studies on Model SystemsJournal of the American Chemical Society, 1958
- Ueber den der Benzoësäure entsprechenden AlkoholEuropean Journal of Organic Chemistry, 1853