Pentacovalent Phosphorus in Organic Synthesis: A New Route to Substituted Phosphonates
- 1 February 1993
- journal article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 75 (1-4), 23-26
- https://doi.org/10.1080/10426509308037355
Abstract
The pentacovalent oxaphospholene derived from methyl vinyl ketone and trialkyl phosphite has been shown to condense with a variety of electrophiles to produce highly substituted phosphonates.Keywords
This publication has 6 references indexed in Scilit:
- α,β-functionalization of enones via pentacovalent oxaphospholenesTetrahedron Letters, 1991
- Pentacovalent oxaphosphorane chemistry in organic synthesis. 2. Total syntheses of (.+-.)-trans- and (.+-.)-cis-neocnidilidesThe Journal of Organic Chemistry, 1991
- Pentacovalent oxaphosphorane chemistry in organic synthesis: a new route to substituted phosphonatesThe Journal of Organic Chemistry, 1991
- Applications of oxaziridines in organic synthesisTetrahedron, 1989
- Asymmetric electrophilic amination: synthesis of .alpha.-amino and .alpha.-hydrazino acids with high optical purityJournal of the American Chemical Society, 1986
- Syntheses via OxyphosphoranesSynthesis, 1974