The first imino-lead complex: synthesis and X-ray characterisation of Pb[µ-NC(But)Ph]3Li·thf (thf = tetrahydrofuran)
- 1 January 1993
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 1086-1088
- https://doi.org/10.1039/c39930001086
Abstract
The title compound, Pb[NButPh]3Li·thf, has been synthesised by nucleophiiic substitution of (C5H5)2 Pb (1 equiv.) with LiNC(But)(Ph)(2equiv.) and shown by X-ray crystallography to have a distorted trigonal bipyramidal PbN3Li core structure in which the phenyl groups of the imino ligands face towards, and encircle, the Pb.Keywords
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