1,5-Asymmetric Induction in Squarate Cascades. Conformational Control of Helicity by Chiral Amino Substituents during Conrotatory Octatetraene Cyclization Prior to β-Elimination
- 27 February 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 63 (6), 2022-2030
- https://doi.org/10.1021/jo9722921
Abstract
No abstract availableKeywords
This publication has 21 references indexed in Scilit:
- Evaluation of Amino Substituents as Nucleofugal Controllers of Regioselectivity and as Chelate Modulators of Stereoselectivity in Squarate Ester CascadesThe Journal of Organic Chemistry, 1998
- Enhanced Channeling of the Squarate Cascade through the Dianionic Oxy-Cope Option. Oxy Substitution Markedly Augments Syn Delivery of the Second AlkenyllithiumJournal of the American Chemical Society, 1997
- Sensitivity of Substitution to the Extent of Self-Immolative Chirality Transfer during Reaction Cascades Originating from Squarate EstersThe Journal of Organic Chemistry, 1997
- Conformational Transmission of Chirality: The Origin of 1,4-Asymmetric Induction in Michael Reactions of Chiral IminesJournal of the American Chemical Society, 1997
- Mapping the Chemical Reactivity of Polyquinanes Produced by 2-fold Addition of Vinyl Anions to Squarate Esters. A Bicyclic Case StudyThe Journal of Organic Chemistry, 1996
- Full control of regioselectivity in linear and angular polyquinane construction from squarate esters by incorporation of a leaving group into a single vinyl anion reactantJournal of the American Chemical Society, 1995
- The Squarate Ester-1,3,5,7-Octatetraene-Polyquinane Cascade: Reaction Efficiency Is Intimately Linked to the Locus of Substitution within the Vinyl AnionJournal of the American Chemical Society, 1995
- Direct elaboration of complex polyquinanes through twofold addition of vinyl anions to squarate estersJournal of the American Chemical Society, 1993
- Stereodynamics of N-ethyl-N-methyl-2-aminobutaneJournal of the American Chemical Society, 1988
- Incremental substituent effects leading to steric blockade of the boat-like six-center Cope rearrangement of cis-1,2-dialkenylcyclobutanesJournal of the American Chemical Society, 1972