Simple Potential Functions for HF and [F–H··F]−
- 1 October 1947
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 15 (10), 739-741
- https://doi.org/10.1063/1.1746309
Abstract
Calculations based on an electrostatic model have been made of the stabilizing energy in [F–H··F]−. The terms used have first been tested on the HF molecule and the distortion of the latter in the bifluoride ion is estimated. The calculated value of —ΔU for [F–H··F]− is 47.3 kcal. per g ion, in satisfactory accord with thermochemical estimates.Keywords
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