Infrared double resonance of SF6 with a tunable diode laser. II. Line shape analysis
- 15 February 1981
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 74 (4), 2189-2194
- https://doi.org/10.1063/1.441379
Abstract
Two‐ and three‐level diode–infrared laser double resonance experiments in SF6 are modeled in terms of a superposition of noninteracting pairs of levels. The Mollow or Hänsch–Toschek line shape functions give a good representation of the observed spectra, with all features describable as either saturated or Stark‐modulated transitions. No evidence for intramolecular coupling is seen at v3=1 of SF6.Keywords
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