Synthese und Eigenschaften neuartiger eindimensionaler Leiter, 7 [1]. Poly-trans(alkinyl)phthalocyaninatosihcium(IV) / Synthesis and Properties of a New Kind of One-Dimensional Conductors. Poly-trans(alkynyl)phthalocyaninatosilicon (IV)

Abstract

Dichloro(phthalocyaninato)silicon(IV) (1) reacts with various bis-bromomagnesium- alkynes to form the corresponding poly-trans(alkynyl)phthalocyaninat osilicon(IV) compounds (5), (11) and (18). The electrical conductivity of 5, 11 and 13 was measured with and without doping.