Self-healing kinetics and the stereoisomers of dicyclopentadiene

Abstract

While original epoxy resin-based self-healing systems used the commercially available endo -isomer of dicyclopentadiene (DCPD), the exo -stereoisomer is known to have much faster olefin metathesis reaction rates with first-generation Grubbs' catalyst. Here, we measure the energy to failure of healed specimens as a function of healing time and compare the kinetics of damage repair for endo - and exo -DCPD, and mixtures of the two isomers. Using catalyst loading levels previously reported to be effective for endo -DCPD, exo -DCPD was found to heal approximately 20 times faster than the endo- isomer, but with a lower healing efficiency. The fracture toughness of the repaired specimens decreased when the exo content of the blends was greater than 40% and, for the pure exo -DCPD, when the catalyst loadings were below 1%. Possible causes of the reduced healing efficiencies of the exo -DCPD healing agent are discussed.