RAMAN SPECTROSCOPIC STUDIES OF SOME URANYL NITRATE COMPLEXES
- 1 April 1978
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 8 (1), 35-39
- https://doi.org/10.1080/00958977808073067
Abstract
Laser Raman spectra of uranyl trinitrate complexes (KUO2(NO3)3, RbUO2(NO3)3, CsUO2(NO3)3, NH4UO2(NO3)3) have been measured in the region from 2000 cm−1 to 10 cm−1. Vibrational assignments have been made on the assumption that all the complexes contain discrete UO2X3 − (X = NO3) ions belonging to a point group of D3h. A brief discussion is made on the ligation effect of nitrate group on the uranyl bond order from a point of view of molecular orbital theory.Keywords
This publication has 11 references indexed in Scilit:
- INFRARED SPECTROSCOPIC STUDIES OF SOME URANYL NITRATE COMPLEXESJournal of Coordination Chemistry, 1976
- Infrared spectra of matrix-isolated UO+2 and NO−2The Journal of Chemical Physics, 1976
- Infrared spectra of matrix-isolated uranium oxide species. I. The stretching regionThe Journal of Chemical Physics, 1973
- Uranium-fluorine lattice vibration of uranyl fluorideJournal of Inorganic and Nuclear Chemistry, 1971
- The low frequency infrared and Raman spectroscopic studies of some uranyl complexes: the deformation frequency of the uranyl ionCanadian Journal of Chemistry, 1970
- Raman and infrared spectroscopic studies of the uranyl ion: the symmetric stretching frequency, force constants, and bond lengthsJ. Chem. Soc. A, 1969
- Infrared spectra of some uranyl nitrate complexesJournal of Inorganic and Nuclear Chemistry, 1967
- Infra-red assignments and force constants in metal—nitrato complexesSpectrochimica Acta, 1965
- Electronic Structure, Spectra, and Magnetic Properties of Oxycations. III. Ligation Effects on the Infrared Spectrum of the Uranyl IonThe Journal of Chemical Physics, 1961
- The electronic structure, spectra, and magnetic properties of actinyl ionsJournal of Molecular Spectroscopy, 1961