Xenon as a Complex Ligand: The Tetra Xenono Gold(II) Cation in AuXe 4 2+ (Sb 2 F 11 − ) 2
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- 6 October 2000
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 290 (5489), 117-118
- https://doi.org/10.1126/science.290.5489.117
Abstract
The first metal-xenon compound with direct gold-xenon bonds is achieved by reduction of AuF3 with elemental xenon. The square planar AuXe4 2+ cation is established by a single-crystal structure determination, with a gold-xenon bond length of approximately 274 picometers. The bonding between gold and xenon is of the σ donor type, resulting in a charge of approximately 0.4 per xenon atom.Keywords
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