cis-Dichloro-(1 ,5-bisdiphenylphosphanopentane)platinum(II). Synthese, Krystall– und Molekülstruktur / cis-Dichloro-(1 ,5-bisdiphenylphosphanopentane)platinum(II). Synthesis, Crystal and Molecular Structure

Abstract

The title compound has been prepared in high yield from K₂[PtCl₄] and 1,5-bis(diphenylphosphano) pentane in dry CH₂Cl₂. The crystals are monoclinic, space group P2₁/c with lattice parameters a = 11.733(3), b = 17.229(5), c = 13.743(4) Å, and β= 92.37(3)°; Z = 4. An X-ray analysis shows that the complex is monomeric and that it has a planar cis-configuration.