Syntheses and Structures of Dinuclear Palladium(II) and Platinum(II) Complexes with (2S,3S)-2,3-Diaminobicyclo[2.2.1]heptane
- 1 December 1993
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 66 (12), 3818-3821
- https://doi.org/10.1246/bcsj.66.3818
Abstract
Dinuclear complexes bridged by optically active diamines, [Pd2Cl2(SS-nbn)3]Cl2·4H2O (1) and [Pt2(en)2(SS-nbn)2]Cl4 (2) (SS–nbn = (2S,3S)–2,3–diaminobicyclo[2.2.1]heptane, en = ethylenediamine) were prepared and characterized by X-ray crystallography for 1. Pd(II) centers are square-planarly coordinated by Cl and three N of three bridging SS-nbn. Molecule 2 has been suggested to have two μ-SS-nbn and two chelating en.Keywords
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