Abstract
Time-dependent gain measurements of a pulsed iodine laser amplifier have been used to deter-mine decay rates of excited iodine atoms 52P1/2 . Rate constants are reported for the iodine deactivation by CF3I and C2F6 . Attempts to correlate the results with predictions from a kinetic model indicate that excited iodine atoms are formed not only in the primary photolysis but also by additional chemical processes.