On the reactions of N2 with O

Abstract

Unimolecular decomposition of N₂O, quenching of O(¹D) by N₂, and vibrational relaxation of N₂ in the presence of O(³P) are all believed to occur by the same curve crossing mechanism. This mechanism is examined making use of a complete theory of curve crossings that we have developed earlier. Good agreement with experiment is found for the unimolecular decomposition rate. The simple curve crossing mechanism does not explain the observed O(¹D) quenching rate; this rate must be due to complex formation and/or additional crossings. At high temperatures, the calculated vibrational relaxation time is in good agreement with experiment, but at low temperatures there is a serious, unexplained discrepancy.