Ion—Defect Pair Dissociation in Compensated Crystalline Lattices

1 September 1971

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 55 (5), 2532-2537
https://doi.org/10.1063/1.1676444

Abstract

A theory is presented to describe ionic distributions in compensated crystalline lattices in the intermediate temperature region in which dissociation of ion—defect pairs becomes significant. A conceptual model of an assembly of independent ion—defect pairs in equilibrium with unassociated ions and defects is introduced. The problem of volume exclusion evolves as a natural consequence in the interpretation of the model. Calculations for the KCl:Sr2+, and NaCl:Sr2+ systems are displayed and related to transport properties.

Keywords

CONCEPTUAL MODEL

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