Ground State of Solid
- 1 June 1962
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 126 (5), 1724-1736
- https://doi.org/10.1103/physrev.126.1724
Abstract
A ground-state wave function for solid in the body-centered cubic phase is calculated in the form of a product of single-particle orbitals and pair correlations. The correlation part is an eigenfunction of the Pluvinage Hamiltonian with each pair in a state of zero energy in a frame in which their center of mass is at rest. Assuming that exchange effects are small, we obtain an approximate single-particle probability function from this wave function. The many-body energy is obtained from this single-particle probability function from basic principles by a plausibility argument, and leads to a pressure-volume relation that is in good agreement with observation. Exchange effects arise from the original wave function, when suitably antisymmetrized. This predicts an exchange energy of about 0.005°K near the melting curve, in agreement with a recent experiment of Adams, Meyer, and Fairbank; this exchange energy favors antiferromagnetic alignment.
Keywords
This publication has 16 references indexed in Scilit:
- Application of Wave Functions Containing Interelectron Coordinates. II. Approximate Energy Levels of AtomsPhysical Review B, 1960
- Theory of SolidPhysical Review B, 1960
- Application of Wave Functions Containing Interelectron Coordinates. I. The Ground-State Energy of LithiumPhysical Review B, 1959
- Structure of theandForms of SolidPhysical Review B, 1958
- Eigenvalues and Eigenfunctions of a Bose System of Hard Spheres and Its Low-Temperature PropertiesPhysical Review B, 1957
- Nuclear Many-Body ProblemPhysical Review B, 1956
- Many-Body Problem with Strong ForcesPhysical Review B, 1955
- Quantum Theory of Many-Particle Systems. I. Physical Interpretations by Means of Density Matrices, Natural Spin-Orbitals, and Convergence Problems in the Method of Configurational InteractionPhysical Review B, 1955
- The Nonadditivity of the Repulsive Potential of HeliumThe Journal of Chemical Physics, 1953
- The low-temperature properties of gaseous helium. IIProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1941