Preparation of the High-Tc Phase of Bi-Sr-Ca-Cu-O Superconductor

Abstract

Co-decomposition of mixed nitrates of Bi, Pb, Sr, Ca and Cu around 830°C under low oxygen pressure led to the formation of a high-T _c superconducting phase of Bi(Pb)-Sr-Ca-Cu-O with T _c(zero) at 107.5 K. A sample prepared by a conventional solid state reaction method under low oxygen pressure also showed the superconducting transition at 107.5 K. X-ray powder diffraction and magnetic susceptibility measurements on these samples revealed the high-T _c phase without 80 K or semiconducting phase. The reaction under low oxygen pressure has an effect to lower the temperature with broad ranges to render the high-T _c phase of the Bi-Sr-Ca-Cu-O.