Soil-lime reaction and microstructural development at elevated temperatures
- 1 September 1986
- journal article
- Published by Mineralogical Society in Clay Minerals
- Vol. 21 (3), 279-292
- https://doi.org/10.1180/claymin.1986.021.3.03
Abstract
Mineralogical analysis of Devonian Red Marl using XRD, TEM, SEM and EDAX showed that it consisted of illite, quartz, and feldspar with minor amounts of chlorite and hematite. Physico-chemical changes in the soil minerals on reaction with lime (calcium hydroxide) from one day up to two years were investigated by these techniques to gain information on the soil-lime reaction mechanism. Significant reaction of the soil minerals and lime was found to occur only at elevated temperatures (50–75°C) in a moist environment. At these temperatures, formation, growth and development of fibrous and foil-like cementitious material was observed. XRD analysis provided no strong evidence for the formation of new phases. TEM analysis and EDAX, however, showed that the newly-formed fibrous and foil-like material consisted of an amorphous calcium silicate aluminate hydrate gel, similar to the gels formed during hydrothermal treatment of lime-silica, but with lower calcium to silicon ratios than previously reported for such gels. The morphological development of the gel suggested that it formed as a result of the progressive breakdown of the clay component in the soil by reaction with the calcium ions from the lime.Keywords
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