Diagonalization of a Molecular-Exciton Hamiltonian for an Impure Crystal
- 15 November 1968
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 49 (10), 4537-4539
- https://doi.org/10.1063/1.1669908
Abstract
The molecular‐exciton Hamiltonian derived by Agranovitch {Zh. Eksp. Teor. Fiz. 37, 430 (1960) [Sov. Phys.—JETP 10, 307 (1960)]} has been diagonalized for a crystal containing a single isotopic impurity molecule. Unlike previous treatments, terms corresponding to the coupling of one‐exciton and many‐exciton states are not neglected. The results are compared with a classical theory.Keywords
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