Novel insertion of acetylene into σ-alkynyl palladium complexes

1 January 1975

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 2,p. 54-55
https://doi.org/10.1039/c39750000054

Abstract

trans-[(PEt₃)₂PdCl(CCPh)] reacts with di-methyl acetylenedicarboxylate to give an insertion product, trans-[(PEt₃)₂PdCl {C(CO₂Me)C(CO₂Me)CC-Ph}], a type important in acetylene catalytic oligomerisation processes.

Keywords

REACTS
PALLADIUM
GIVE
ALKYNYL
OLIGOMERISATION
ACETYLENEDICARBOXYLATE
METHYL

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