A New Synthetic Route to Methylenomycin B Via Rhodium(II)-Mediated Decomposition of α,β-Unsaturated α'-Diazoketones
- 1 January 1991
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 21 (1), 17-23
- https://doi.org/10.1080/00397919108020785
Abstract
A new synthesis of methylenomycin B, involving Rh(II)-catalyzed, intramolecular carbon-hydrogen insertion of diazoketone 2c, derived from 2,3-dimethyl-2-butenoic acid 2b, is reported.Keywords
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