On the formation of (triphenylphosphine)(ethylene)pentamethylcyclopentadienylrhodium(I) in the reaction of diiodo(triphenylphosphine)pentamethylcyclopentadienylrhodium(III) with butane-1,4-bis(magnesium bromide). An example of facile CO cleavage of diethyl ether by an organomagnesium compound
- 30 January 1979
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 165 (2), 253-263
- https://doi.org/10.1016/s0022-328x(00)94327-4
Abstract
No abstract availableKeywords
This publication has 13 references indexed in Scilit:
- Preparation and reactions of phosphine nickelocyclopentanesJournal of the American Chemical Society, 1978
- Crystal structure of .eta.5-pentamethylcyclopentadienyltriphenylphosphineethylenerhodium(I). A case of important .pi. component in a metal-olefin bondJournal of the American Chemical Society, 1978
- The relationship between metallacyclopentanes and bis(olefin)-metal complexesJournal of the American Chemical Society, 1978
- Selective olefin dimerization via tantallocyclopentane complexesJournal of the American Chemical Society, 1978
- Metallacycloalkane chemistry: synthesis of the first palladacyclopentane derivative and its transformation into a η3-butenyl cationic complexJournal of the Chemical Society, Chemical Communications, 1978
- Synthesis and crystal structures of the metallacyclopentane complexes (η5-cyclopentadienyl)(triphenylphosphine)(butane-1,4-diyl)cobalt(III) and (η5-pentamethylcyclopentadienyl)(triphenylphosphine)-(butane-1,4-diyl)iridium(III)Journal of the Chemical Society, Chemical Communications, 1977
- Five-, six-, and seven-membered rhodacycloalkanes from [RhI2(PPh3)(η5-C5Me5)] and BrMg–[CH2]n–MgBr (n= 4,5, or 6). Occurrence of carbon–carbon σ-bond cleavage in the preparation of the rhodacyclopentane derivativeJournal of the Chemical Society, Chemical Communications, 1977
- Synthesis and reactions of bis(cyclopentadienyl)titanium(IV) metallocyclesJournal of the American Chemical Society, 1976
- Possible intermediate in the tungsten-catalyzed olefin metathesis reactionJournal of the American Chemical Society, 1972
- The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivativesJ. Chem. Soc. A, 1966