Synthesis of Furan-2,5-dicarbaldehyde by Oxidation of 5-Silyloxymethyl-2-furfural
- 1 April 1994
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 24 (7), 939-944
- https://doi.org/10.1080/00397919408020768
Abstract
Oxidation of alkyl silyl ethers of 5-hydroxymethyl-2-furfural to furane-2,5-dicarbaldehyde is promoted by N-bromosuccinimide in the presence of azoisobutyronitrile. The influence of solvent has been studied. Using 1,2-dichloromethane or dodecane as solvent, good yields are obtained from the trimethylsilyl or tert-butyldimethylsilyl derivatives.Keywords
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