AN ALKYL-SUBSTITUTED INDIUM(I) TETRAMER
- 23 September 1993
- journal article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 30 (1), 25-28
- https://doi.org/10.1080/00958979308022744
Abstract
The first indium(I) alkyl, [InC(SiMe3)3]4 (1), has been prepared by treatment of InCl with LiC(SiMe3)3·2 THF in Et2O solution. Compound 1 crystallizes in the space group Pnma with a=30.465(2), b=13.855(2), c=17.824(2)Å, and Z=4. Individual molecules of 1 feature a tetrahedral In4 core with an average indium-indium distance of 3.09(2)Å.Keywords
This publication has 7 references indexed in Scilit:
- Bis(trisyl)oxadiboriraneAngewandte Chemie International Edition in English, 1992
- TII‐TII Interactions in the Molecular State—an MO AnalysisAngewandte Chemie International Edition in English, 1989
- Synthesis and crystal structure of pentabenzylcyclopentadienylindium(I)Journal of Organometallic Chemistry, 1989
- Synthesis, characterization and structural studies of In(C5H4Me) by x-ray diffraction and electron diffraction techniques and a reinvestigation of the crystalline state of In(C5H5) by x-ray diffraction studiesOrganometallics, 1988
- Synthesis and crystal and molecular structure of In(C5Me5) - an apparent octahedral clusterJournal of the American Chemical Society, 1986
- Novel alkylmetal hydroxides. The crystal and molecular structures of bis(µ-hydroxy)-bis{tris(dimethylphenylsilyl)methylzinc}, [{Me2PhSi)3CZnOH}2] and µ4-oxohexa(µ-hydroxy)tetrakis{tris(trimethylsilyl)methylindium}, [O{(Me3Si)3Cln}4(OH)6]Journal of the Chemical Society, Chemical Communications, 1986
- Crystal structure of the tetrahydrofuran adduct of tris(trimethylsilyl)-methyl-lithium, [Li(thf)4][Li{C(SiMe3)3}2], an ate derivative of lithiumJournal of the Chemical Society, Chemical Communications, 1983