Calculation of the Detonation Properties of Solid Explosives with the Kistiakowsky-Wilson Equation of State

Abstract

The Kistiakowsky‐Wilson equation of state, pV_g = RT(1+xe^βx), where x = k/V_g(T+θ)^α, for the gaseous detonation products of solid explosives has been re‐examined in the light of new experimental data on detonation pressure and on the variation of detonation velocity D with loading density ρ₀ for several RDX/TNT mixtures. The value β = 0.30 used in the past is too high to match the observed slopes of the D—ρ₀ curves. The old value α = 0.25 is too small to match the experimental Chapman‐Jouguet pressure of most of these explosives, but too large to match the pressure of pure TNT. A suitable compromise for the explosives considered is α = 0.5, β = 0.09, θ = 400°K.