Enzyme-Mediated Enantioface-Differentiating Hydrolysis of Enol Esters
- 1 September 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (9), 1589-1592
- https://doi.org/10.1246/cl.1989.1589
Abstract
A new type of enzymatic hydrolysis has been disclosed. A kind of yeast, Pichia miso, hydrolyzed enol esters such as 3-acetoxy-1-p-methoxybenzyloxy-2-methoxymethoxy-2-alkenes with differentiation of the enantiotopic face to afford optically active α-substituted ketones.Keywords
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