Factors Influencing Characteristic Vibrational Frequencies of Molecules: Intramolecular Effects
- 1 August 1956
- journal article
- research article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 10 (3), 115-123
- https://doi.org/10.1366/000370256774633755
Abstract
This paper is concerned with the intramolecular factors which make a characteristic group frequency vary slightly from one type of compound to another. The factors which are discussed with numerous examples include atomic mass, mechanical coupling, symmetry, electronegativity, conjugation and bond-angle strain.Keywords
This publication has 13 references indexed in Scilit:
- Relation between the Electronegativities of Adjacent Substitutents and the Stretching Frequency of the Carbonyl GroupJournal of the American Chemical Society, 1955
- Vibrational Spectra and Possible Structures of the Dimers of Cycloöctatetraene1Journal of the American Chemical Society, 1954
- Strong Hydrogen Bonds in CrystalsThe Journal of Chemical Physics, 1953
- Infra-Red Dichroism and Protein StructureNature, 1952
- Infrared Absorption Band Due to Nitrile Stretching VibrationAnalytical Chemistry, 1952
- The Infrared Spectra and Structures of the Iron Carbonyls1Journal of the American Chemical Society, 1950
- The Infrared Spectra of a Number of Isomeric Normal Acetylenic CompoundsJournal of the American Chemical Society, 1949
- 294. The application of infra-red spectroscopy to structural problems in the anthraquinone fieldJournal of the Chemical Society, 1948
- The Use of Deuterium in the Analysis of Vibrational SpectraReviews of Modern Physics, 1947
- XX, On the influence of the atomic grouping in the molecules of organic bodies on their absorption in the infra-red region of the spectrumPhilosophical Transactions of the Royal Society of London, 1881