Intercalation of two-dimensional oxalate-bridged molecule-based magnets into layered double hydroxide hosts
- 24 September 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 20 (42), 9476-9483
- https://doi.org/10.1039/c0jm01722a
Abstract
Here we report the intercalation of a MnII –CrIII oxalate-bridged extended network into the interlamellar space offered by a ZnII –AlIII LDH host. This material exhibits ferrimagnetic ordering below 3 K from dominant antiferromagnetic interactions between metallic centres through the oxalate linker. Our result opens the door for the design of a completely new sort of hybrid magnetic multilayers from molecule-based magnets and layered inorganic flexible hosts, where the intrinsic properties of both sub-layers can be combined.Keywords
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