Ferroelectric Porous Molecular Crystal, [Mn3(HCOO)6](C2H5OH), Exhibiting Ferrimagnetic Transition
- 1 November 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (47), 15074-15075
- https://doi.org/10.1021/ja0665390
Abstract
A porous molecular crystal with guest ethanol molecules, [Mn3(HCOO)6](C2H5OH), was found to be a new type of multifunctional molecular system, which exhibits a ferroelectric transition at 165 K and a ferrimagnetic transition at 8.5 K. [Mn3(HCOO)6](C2H5OH) will give a hint to design “multiferroic” molecular materials where ferroelectric and ferromagnetic orders coexist.Keywords
This publication has 7 references indexed in Scilit:
- Magnetic Reversal of the Ferroelectric Polarization in a Multiferroic Spinel OxidePhysical Review Letters, 2006
- Dielectric Properties of Porous Molecular Crystals That Contain Polar MoleculesAngewandte Chemie International Edition, 2005
- Methane and Carbon Dioxide Storage in a Porous van der Waals CrystalAngewandte Chemie International Edition, 2005
- A route to high surface area, porosity and inclusion of large molecules in crystalsNature, 2004
- Mn3(HCOO)6: a 3D porous magnet of diamond framework with nodes of Mn-centered MnMn4tetrahedron and guest-modulated ordering temperatureChemical Communications, 2004
- Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework MaterialScience, 2002
- Superexchange interaction and symmetry properties of electron orbitalsJournal of Physics and Chemistry of Solids, 1959