17- and 19-Electron Complexes [FeIII(η5-C5R5)(S2CNMe2)L]n+ (n = 1, 0): Electronic Structure and Substitution and Redox Chemistry. Formation of [FeIV(η5-C5R5)(dtc)2] and Characterization of both 17e and 19e States of a Transition-Metal Complex
- 1 January 1996
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 118 (17), 4133-4147
- https://doi.org/10.1021/ja953603x
Abstract
No abstract availableThis publication has 57 references indexed in Scilit:
- Metal Atom Synthesis and Structure of (.eta.6-Toluene)bis(trichlorosilyl)iron Dihydride: An Unusual Iron(IV) ComplexJournal of the American Chemical Society, 1994
- High valent transition metal chemistry. Synthesis and characterization of an intermediate-spin iron(IV) complex of a strong .pi.-acid ligandJournal of the American Chemical Society, 1992
- Theoretical studies of inorganic and organometallic reaction mechanisms. 5. Substitution reactions of 17- and 18-electron transition-metal hexacarbonyl complexesInorganic Chemistry, 1992
- Organometallic electron-reservoirs. 37. Electron-transfer chemistry of the 20-electron complex [Fe0(C6Me6)2] and of the 19-electron complex [FeI(C6Me6)(.eta.5-C6Me6H)]: mild carbon-hydrogen activation by oxygen via superoxide ion and functionalization of the exocyclic methylenes in the resulting complexes [Fe0(C6Me6)(.eta.4-polyene)]Organometallics, 1990
- Synthetic and x-ray structural studies on pentabenzylcyclopentadienyl derivatives of manganese, rhenium, and ironOrganometallics, 1989
- Organometallic electron reservoirs. 33. Redox systems involving stable 17-electron iron(III)-methyl complexesOrganometallics, 1987
- Electrochemical reduction of protonated cyclopentadienylcobalt phosphine complexesInorganic Chemistry, 1986
- Electron-transfer pathways in the reduction of d6 and d7 organoiron cations by lithium tetrahydroaluminate and sodium tetrahydroborateJournal of the American Chemical Society, 1982
- Syntheses, characterizations, and stereoelectronic stabilization of organometallic electron reservoirs: the 19-electron d7 redox catalysts .eta.5-C5R5Fe-.eta.6-C6R'6Journal of the American Chemical Society, 1981
- An Electron Paramagnetic Resonance Study of Metal-Aromatic Bonding in Bis(hexamethylbenzene)iron(I)Journal of the American Chemical Society, 1966