Theoretical study of autoionising states of molecules. II. The1Σu+and1Πgstates of H2
- 14 September 1986
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 19 (17), 2611-2615
- https://doi.org/10.1088/0022-3700/19/17/010
Abstract
Using Feshbach's projection operator formalism, the adiabatic potential energies and energy widths of the lowest 1 Sigma u+ and 1 Pi g autoionising states of the H2 molecule are calculated in the region of internuclear distance R from 1.0 to 3.0 au (3.6 au for the 1 Sigma u state). The energy curve and energy width for the 1 Sigma u+ state agree with other calculations. The accuracy of the energy curve and width for the 1 Pi g state is discussed.Keywords
This publication has 11 references indexed in Scilit:
- Vibrationally and rotationally resolved cross sections and angular distributions of photoelectrons from H2Journal of Physics B: Atomic and Molecular Physics, 1986
- Low-energy electron-H2+collisions: variation of resonance parameters with internuclear separationJournal of Physics B: Atomic and Molecular Physics, 1985
- Theoretical study of autoionising states of molecules; H2and He22+Journal of Physics B: Atomic and Molecular Physics, 1984
- Examination of theresonances in low-energy-collisionsPhysical Review A, 1983
- Theoretical study of the lowestdoubly excited state ofPhysical Review A, 1983
- The doubly excited autoionizing states of H2The Journal of Chemical Physics, 1983
- Two-electron excited states and adiabatic quantum defects of: Analysis of elastic scattering of electrons fromPhysical Review A, 1983
- Linear algebraic approach to electronic excitation of atoms and molecules by electron impactPhysical Review A, 1983
- Autoionising states of He22+ II: potential energy curves and energy widthsJournal of Physics B: Atomic and Molecular Physics, 1982
- Autoionising states of He22+. II. Potential energy curves and energy widthsJournal of Physics B: Atomic and Molecular Physics, 1980