Long-range coupling in a mixed-valence diruthenium complexes containing bis-terpyridine ligands of various lengths as bridges
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 434-435
- https://doi.org/10.1039/c39930000434
Abstract
Dinuclear ruthenium(II) complexes have been prepared which contain back-to-back bis-terpyridine ligands of various lengths (Ru ⋯ Ru distances between 7 and 20 Å) as bridges; significant electronic coupling is observed in mixed-valence states, even for the system with the longest separation.Keywords
This publication has 21 references indexed in Scilit:
- Control of intramolecular electron transfer by a chemical reaction. The 4,4'-azopyridine/1,2-bis(4-pyridyl)hydrazine systemInorganic Chemistry, 1991
- Synthesis and spectroscopic characterization of bis[bis(bipyridine)ruthenium(II)]-3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl and its redox productsInorganic Chemistry, 1990
- Synthesis and characterization of new binuclear electron-transfer models containing rigid aromatic spacersInorganic Chemistry, 1989
- Intervalence transfer in pentammineruthenium complexes of .alpha.,.omega.-dipyridyl polyenesInorganic Chemistry, 1989
- Distance Dependence of Electron Transfer RatesCoordination Chemistry Reviews, 1985
- Mixed Valence Complexes of d 5 ‐ d 6 Metal CentersPublished by Wiley ,1983
- Long-range intervalence electron tunneling through fully saturated systemsJournal of the American Chemical Society, 1982
- Outer-sphere intervalence transferJournal of the American Chemical Society, 1978
- Direct approach to measuring the Franck-Condon barrier to electron transfer between metal ionsJournal of the American Chemical Society, 1969
- Intervalence‐Transfer Absorption. Part 2. Theoretical Considerations and Spectroscopic DataPublished by Wiley ,1967