DISTINCTIVE COORDINATION CHEMISTRY AND BIOLOGICAL RELEVANCE OF COMPLEXES WITH MACROCYCLIC OXO POLYAMINES
- 1 April 1986
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 15 (1), 1-28
- https://doi.org/10.1080/00958978608075853
Abstract
Replacement of amine with amide groups in macrocyclic polyamines yields a novel series of oxo polyamine ligands which are the hybrids of macrocyclic polyamines and linear oligopeptides. Due to the involvement of imide anions in coordination, their ligand fields are stronger compared to those of macrocyclic counterparts. One consequence is stabilization of unusual oxidation states CuIII and NiIII.Keywords
This publication has 66 references indexed in Scilit:
- Effects of imide anions and axial donors on the stability and oxidation behavior of square-planar 13-15-membered macrocyclic tetraamine complexes of nickel(II) and copper(II)Inorganic Chemistry, 1984
- A mono-ozygenase model for selective aromatic hydroxylation with nickel(II)-macrocyclic polyaminesJournal of the Chemical Society, Chemical Communications, 1984
- Dioxygen uptake by cobalt(II) complexes of macrocyclic polyamines. Effects of chelate ring size and substituentsInorganic Chemistry, 1983
- Further studies on superoxide dismutase activities of macrocyclic polyamine complexes of copper(II)Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology, 1983
- THE EFFECTS OF SIZE AND DONOR ATOMS OF MACROCYCLIC POLYAMINES BINDING TO Mg2+ AND Ca2+Chemistry Letters, 1982
- Reactions of copper(III) tetraglycineInorganic Chemistry, 1980
- Ligand effects on the thermodynamic stabilization of copper(III)-peptide complexesJournal of the American Chemical Society, 1977
- Kinetics of copper(II)-glycylglycyl-L-histidine reactions. Acid decomposition and proton-assisted nucleophilic displacement by triethylenetetramineJournal of the American Chemical Society, 1976
- The stabilization of trivalent nickel in deprotonated-peptide complexesJournal of the American Chemical Society, 1976
- Crystal and molecular structure of di(perchlorato)(1,4,8,11-tetraazacyclotetradecane)copper (II). Cu(cyclam) (ClO4)2Journal of Chemical Crystallography, 1975