Multiple Bonding in Heavier Element Compounds Stabilized by Bulky Terphenyl Ligands
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- 1 November 2007
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 46 (24), 10047-10064
- https://doi.org/10.1021/ic700813h
Abstract
This paper summarizes recent developments involving the preparation and reactivity of molecular species stabilized by terphenyl ligands that feature new bonding environments. Highlights include the synthesis and characterization of dimetallenes and dimetallynes, ArEEAr [E = heavy group 13 (triel) or group 14 (tetrel) element, Ar = terphenyl ligand] and, more recently, the synthesis of a stable chromium(I) dimer, ArCrCrAr, that displays a 5-fold bonding interaction between the chromium centers.Keywords
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