The (g) tensor of D4hcomplexes formed by d9ions
- 14 September 1976
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 9 (17), 3277-3284
- https://doi.org/10.1088/0022-3719/9/17/020
Abstract
In order to improve the understanding of the (g) tensor of D4h complexes formed with d9 ions, using the more realistic molecular orbital approach, the third-order contribution tensor (G) has been calculated. The results obtained have been applied to the analysis of the (g) tensor of (CuCl4)2-D4h complex, also including the second-order contribution tensor ( delta g) arising from the bonding levels B2g and Eg.Keywords
This publication has 30 references indexed in Scilit:
- Dichroic Optical Absorptions and Thermal Reorientation of Jahn-Teller Distorted Ag2+Centers in CbCl2Journal of the Physics Society Japan, 1975
- Lattice Effects on the Electron Paramagnetic Resonance Spectrum of a Copper(II) ComplexPhysica Status Solidi (a), 1975
- Vibronically Allowedd-dTransitions of Cu2+Centers in CdCl2and CbBr2Journal of the Physics Society Japan, 1974
- The effect of covalency on the spin—orbit coupling constantChemical Physics Letters, 1973
- Observation of Cu2+ In SrCl2 crystalsPhysics Letters A, 1973
- EPR Spectrum of a Jahn-Teller System, NaCl:Physical Review B, 1970
- Paramagnetic resonance and optical absorption of trapped holes and electrons in irradiated KCI: AgProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1963
- Paramagnetic resonance in diluted copper salts III. Theory, and evaluation of the nuclear electric quadrupole moments of 63 Cu and 65 CuProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1955
- Paramagnetic resonance in diluted copper salts II. Salts with trigonal symmetryProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1955
- The theory of the nuclear hyperfine structure of paramagnetic resonance spectra in the copper Tutton saltsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1951