Absolute Configuration of 4-α-D-Glucopyranosyl-myo-inositol, Enzymatic Transglycosylation Product
- 1 September 1993
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 12 (6), 685-692
- https://doi.org/10.1080/07328309308018999
Abstract
The absolute configuration of 4-α-D-glucopyranosyl-myo-inositol, one of the enzymatic transglycosylation products from cyclodextrin to myo-inositol, was confirmed by chemical synthesis. The glycosylation was shown to proceed in a highly diastereoselective manner by HPLC analysis of the chemically synthesized racemic glycoside.Keywords
This publication has 5 references indexed in Scilit:
- Synthesis of glucosyl-inositol using a CGTase, isolation and characterization of the positional isomers, and assimilation profiles for intestinal bacteriaBiotechnology Letters, 1992
- Easy access of optically active myo-inositol derivatives by enantioselective acylation using a tartaric acid monoesterTetrahedron Letters, 1990
- Comparison of catalysts in α-glucosylation reactions and identification of triflic anhydride as a new reactive promoter.Tetrahedron Letters, 1990
- Synthesis of 6-0-(α-D-mannopyranosyl)-D-myo-inositol: a fragment from mycobacteria phospholipidsTetrahedron, 1990
- Synthesis of D-myo-inositol 1,3,4,5-tetrakisphosphateTetrahedron Letters, 1987