Dissociation and Isomerization of Vibrationally Excited Species. III
- 15 October 1965
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 43 (8), 2658-2661
- https://doi.org/10.1063/1.1697191
Abstract
The equations of Part I for the specific and over‐all unimolecular reaction‐rate constants are extended slightly by including centrifugal effects in a more detailed way and by making explicit allowance for possible reaction‐path degeneracy (optically or geometrically isomeric paths). The expression for reaction‐path degeneracy can be applied to other types of reactions in discussions of statistical factors in reaction rates.Keywords
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