Desorption of Surface Positrons: A Source of Free Positronium at Thermal Velocities

Abstract
A direct measurement is reported of the velocity of positronium (Ps) ejected into a vacuum when 0- to 100-eV positrons (e+) strike a negatively biased Cu(111) surface. At 30°C, about half the e+ form Ps with normal energy component E¯=3.4(3) eV. At 790°C, most of the remaining e+ form Ps but with E¯=0.14(1) eV, and a non-Maxwellian thermal distribution. We infer that surface-bound e+ are thermally desorbed to form the extra Ps. These low Ps velocities suggest exciting possibilities for experiments on free Ps.