Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO₅–OEt₂). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

1 January 1970

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications

No. 22,p. 1550-1551
https://doi.org/10.1039/c29700001550

Abstract

The title epidioxy-ketone was isolated using diperoxychromium(VI) oxide etherate as an oxygenating reagent in a reaction which may involve singlet oxygen as an intermediate.

Keywords

CRO5
DIPEROXYCHROMIUM
ETHERATE
SINGLET OXYGEN
TITLE
TETRAPHENYL
OET2

Cited by 15 articles

Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO5–OEt2). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)

Abstract

Keywords

Oxygenation reactions of diperoxychromium(VI) oxide etherate (CrO₅–OEt₂). Possible role of singlet oxygen in the isolation of 1,2,3,4-tetraphenyl-5,6-dioxabicyclo[2,2,1]hept-2-en-7-one (tetracyclone endoperoxide)