Reactions of Dimesityldioxoosmium(VI) with Bidentate N-Heterocycles. Crystal Structure of a Dioxoosmium(VI) Complex Containing a Molecular Square
- 5 March 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (5), 1497-1501
- https://doi.org/10.1021/om950531+
Abstract
No abstract availableKeywords
This publication has 18 references indexed in Scilit:
- Oxo-Bridged Linear Diosmium Complexes with Unsymmetric Ligand Environment. Structures of the Diosmium(IV,IV) Complex, [(py)2Cl2(CH3COO)Os(.mu.-O)Os(py)2Cl3] (py = pyridine) and Its Mixed-Valence (III,IV) AnalogInorganic Chemistry, 1995
- Metal–oxo photooxidants. Crystal structure, spectroscopy and photophysical properties of neutral luminescent trans-dioxoosmium(VI) complexes with cyanide and mesityl ligandsJ. Chem. Soc., Dalton Trans., 1995
- Preparation and characterization of a macrocyclic tetraaryltetraiodonium compound, cyclo(Ar4I4)4+.cntdot.4X-. A unique, charged, cationic molecular boxJournal of the American Chemical Society, 1993
- Reductive quenching of the emission of trans-dioxo(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)osmium(VI) in waterInorganic Chemistry, 1993
- Osmium imido complexes: synthesis, reactivity, and SCF-X.alpha.-SW electronic structureInorganic Chemistry, 1991
- Syntheses, spectroscopy, and electrochemistry of high-valent osmium(V) and -(VI) oxo complexes of macrocyclic tertiary amine ligandsJ. Chem. Soc., Dalton Trans., 1990
- Reactions of dimesityldioxo-osmium(VI) with donor ligands; reactions of MO2(2,4,6-Me3C6H2)2, M = Os or Re, with nitrogen oxides. X-Ray crystal structures of [2,4,6-Me3C6H2N2]+[OsO2(ONO2)2(2,4,6-Me3C6H2)]–, OsO(NBut)(2,4,6-Me3C6H2)2, OsO3(NBut), and ReO3[N(2,4,6-Me3C6H2)2]J. Chem. Soc., Dalton Trans., 1990
- Metal–oxo photo-oxidants. Photochemistry and photophysics of trans-[OsVI(tmc)(O)2]2+(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) and trans-[OsVI(CN)4(O)2]2–Journal of the Chemical Society, Chemical Communications, 1987
- Novel UV-vis spectral feature and electrochemical behavior of high-valent osmium(VI) dioxo complex of 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (TMC). Reversible three-electron redox couple and vibronic structured UV-vis absorption bands involving trans-[Os(VI)(TMC)O2]2+Journal of the American Chemical Society, 1986
- High-valent oxo complexes of osmium as selective oxidants for cyclohexene oxidation. Complexation of the bisamide tetradentate ligand bpb to osmium and the X-ray structure of trans-[osIII(bpb)(PPh3)Cl][bpbH2=N,N′-bis(2′-pyridine-carboxamide)-1,2-benzene]Journal of the Chemical Society, Chemical Communications, 1986